The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 27, 2022

Filed:

Nov. 26, 2017
Applicant:

Hrl Laboratories, Llc, Malibu, CA (US);

Inventors:

Zak C. Eckel, Thousand Oaks, CA (US);

Andrew P. Nowak, Los Angeles, CA (US);

Ashley M. Nelson, Los Angeles, CA (US);

April R. Rodriguez, Los Angeles, CA (US);

Assignee:

HRL Laboratories, LLC, Malibu, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C04B 35/56 (2006.01); B29C 64/10 (2017.01); B28B 1/00 (2006.01); C09D 11/101 (2014.01); C09D 11/037 (2014.01); C04B 35/58 (2006.01); C04B 35/589 (2006.01); C08L 83/08 (2006.01); C04B 35/571 (2006.01); C04B 35/597 (2006.01); C04B 35/515 (2006.01); C04B 35/117 (2006.01); C04B 35/14 (2006.01); C04B 35/44 (2006.01); C04B 35/46 (2006.01); C04B 35/488 (2006.01); C04B 35/532 (2006.01); C04B 35/563 (2006.01); C04B 35/565 (2006.01); C04B 35/581 (2006.01); C04B 35/80 (2006.01); B33Y 40/20 (2020.01); B33Y 70/10 (2020.01); B33Y 40/10 (2020.01); C04B 35/622 (2006.01); C04B 35/628 (2006.01); C04B 35/634 (2006.01); C04B 35/64 (2006.01); C09D 7/61 (2018.01); C09D 11/03 (2014.01); C09D 11/102 (2014.01); B33Y 80/00 (2015.01); B29C 64/379 (2017.01); C09D 7/40 (2018.01); C09D 7/62 (2018.01); C09D 5/33 (2006.01); B29C 35/08 (2006.01); B29C 64/129 (2017.01); B29C 71/02 (2006.01); C08G 77/18 (2006.01); C08G 77/20 (2006.01); C08G 77/28 (2006.01); B29K 105/00 (2006.01); C08K 3/34 (2006.01); B33Y 10/00 (2015.01); B29K 83/00 (2006.01); B29K 509/04 (2006.01); C08K 7/00 (2006.01); C08K 7/10 (2006.01); C08K 9/04 (2006.01);
U.S. Cl.
CPC ...
C04B 35/5603 (2013.01); B28B 1/001 (2013.01); B29C 64/10 (2017.08); B29C 64/379 (2017.08); B33Y 40/10 (2020.01); B33Y 40/20 (2020.01); B33Y 70/10 (2020.01); B33Y 80/00 (2014.12); C04B 35/117 (2013.01); C04B 35/14 (2013.01); C04B 35/44 (2013.01); C04B 35/46 (2013.01); C04B 35/488 (2013.01); C04B 35/515 (2013.01); C04B 35/532 (2013.01); C04B 35/563 (2013.01); C04B 35/565 (2013.01); C04B 35/5611 (2013.01); C04B 35/5622 (2013.01); C04B 35/571 (2013.01); C04B 35/58 (2013.01); C04B 35/581 (2013.01); C04B 35/589 (2013.01); C04B 35/58014 (2013.01); C04B 35/58028 (2013.01); C04B 35/597 (2013.01); C04B 35/62218 (2013.01); C04B 35/62836 (2013.01); C04B 35/62839 (2013.01); C04B 35/63448 (2013.01); C04B 35/64 (2013.01); C04B 35/80 (2013.01); C08L 83/08 (2013.01); C09D 5/004 (2013.01); C09D 7/61 (2018.01); C09D 7/62 (2018.01); C09D 7/67 (2018.01); C09D 7/68 (2018.01); C09D 7/69 (2018.01); C09D 7/70 (2018.01); C09D 11/03 (2013.01); C09D 11/037 (2013.01); C09D 11/101 (2013.01); C09D 11/102 (2013.01); B29C 64/129 (2017.08); B29C 71/02 (2013.01); B29C 2035/0827 (2013.01); B29C 2035/0838 (2013.01); B29K 2083/00 (2013.01); B29K 2105/0002 (2013.01); B29K 2509/04 (2013.01); B29K 2995/003 (2013.01); B29K 2995/0026 (2013.01); B33Y 10/00 (2014.12); C04B 2235/3826 (2013.01); C04B 2235/3895 (2013.01); C04B 2235/483 (2013.01); C04B 2235/5216 (2013.01); C04B 2235/5436 (2013.01); C04B 2235/6026 (2013.01); C04B 2235/6562 (2013.01); C04B 2235/6565 (2013.01); C04B 2235/77 (2013.01); C04B 2235/96 (2013.01); C08G 77/18 (2013.01); C08G 77/20 (2013.01); C08G 77/28 (2013.01); C08K 3/34 (2013.01); C08K 7/00 (2013.01); C08K 7/10 (2013.01); C08K 9/04 (2013.01); C08K 2201/005 (2013.01);
Abstract

This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.


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