The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 20, 2022

Filed:

Jun. 03, 2022
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Aasif Helal, Dhahran, SA;

Mohammed Fettouhi, Dhahran, SA;

Md. Eyasin Arafat, Dhahran, SA;

Mohd Yusuf Khan, Dhahran, SA;

Mohammed Ahmed Sanhoob, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/16 (2006.01); C07D 263/52 (2006.01); B01J 38/54 (2006.01); C07D 263/22 (2006.01);
U.S. Cl.
CPC ...
B01J 31/1691 (2013.01); B01J 38/54 (2013.01); C07D 263/22 (2013.01); C07D 263/52 (2013.01);
Abstract

A method of fixating COto form a substituted oxazolidinone is described. The method includes mixing a nickel-based metal-organic framework (Ni-MOF) catalyst of formula [Ni(BTC)(HO)]·(DMF)(HO), a cocatalyst, an aromatic amine, and at least one epoxide to form a reaction mixture, and further contacting the reaction mixture with a gas stream containing carbon dioxide to react the carbon dioxide in the gas stream with the epoxide and the aromatic amine to form a substituted oxazolidinone mixture. The method further includes adding a polar protic solvent to the substituted oxazolidinone mixture, centrifuging, and filtering to produce a recovered Ni-MOF; and further washing the recovered Ni-MOF with an organochloride solvent and drying for at least 5 hours to produce a recycled Ni-MOF.


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