The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Dec. 06, 2022

Filed:

Mar. 31, 2017
Applicant:

The Regents of the University of California, Oakland, CA (US);

Inventors:

Jeffrey R. Long, Oakland, CA (US);

Benjamin K. Keitz, San Francisco, CA (US);

Douglas Reed, Berkeley, CA (US);

Assignee:
Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/22 (2006.01); B01D 53/02 (2006.01); C01B 3/56 (2006.01); B01J 20/28 (2006.01); C01B 32/40 (2017.01); B01D 53/04 (2006.01); B01J 20/34 (2006.01); C07F 15/02 (2006.01);
U.S. Cl.
CPC ...
B01J 20/226 (2013.01); B01D 53/02 (2013.01); B01D 53/04 (2013.01); B01J 20/28066 (2013.01); B01J 20/3425 (2013.01); B01J 20/3483 (2013.01); B01J 20/3491 (2013.01); C01B 3/56 (2013.01); C01B 32/40 (2017.08); C07F 15/025 (2013.01); B01D 2253/204 (2013.01); B01D 2256/10 (2013.01); B01D 2256/16 (2013.01); B01D 2256/22 (2013.01); B01D 2256/24 (2013.01); B01D 2256/245 (2013.01); B01D 2257/102 (2013.01); B01D 2257/104 (2013.01); B01D 2257/502 (2013.01); C01B 2203/042 (2013.01); C01B 2203/047 (2013.01); C01B 2210/002 (2013.01); C01B 2210/0021 (2013.01);
Abstract

An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.


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