The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 29, 2022

Filed:

Nov. 14, 2019
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Paul Hamilton, Hampshire, GB;

Terrance C. Osby, Spring, TX (US);

Brian W. Heins, Humble, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/30 (2006.01); B01D 3/14 (2006.01); B01J 31/22 (2006.01); C07C 7/00 (2006.01); C07C 7/04 (2006.01);
U.S. Cl.
CPC ...
C07C 2/30 (2013.01); B01D 3/141 (2013.01); B01D 3/143 (2013.01); B01J 31/223 (2013.01); C07C 7/005 (2013.01); C07C 7/04 (2013.01); C07C 2531/22 (2013.01);
Abstract

Linear alpha olefins (LAOS) may be formed by oligomerization of ethylene in the presence of a Ziegler-type catalyst. The presence of trace water during oligomerization can result in unwanted formation of insoluble higher oligomers or polymer. Methods for limiting the presence of water during ethylene oligomerization reactions may include separating residual ethylene and 1-butene from an LAO product stream to form a higher LAO-enriched stream comprising CLAOs, separating 1-hexene as an overhead stream from the higher-LAO enriched stream using a first distillation column, obtaining separated solvent as a side stream from the first distillation column or as a side stream from a first of one or more downstream distillation columns, and returning the separated solvent to a reactor in a recycled solvent stream. The recycled solvent stream passes through one or more driers before returning to the reactor.


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