The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 29, 2022

Filed:

Jun. 29, 2018
Applicant:

Wanhua Chemical Group Co., Ltd., Shandong, CN;

Inventors:

Tongji Wang, Shandong, CN;

Fei Ye, Shandong, CN;

Lei Wang, Shandong, CN;

Naibo Chu, Shandong, CN;

Lichao Yang, Shandong, CN;

Kang Sun, Shandong, CN;

Yuan Li, Shandong, CN;

Weiqi Hua, Yantai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 21/06 (2006.01); C07D 301/19 (2006.01); B01J 21/08 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01); B01J 37/04 (2006.01); B01J 37/08 (2006.01);
U.S. Cl.
CPC ...
B01J 21/08 (2013.01); B01J 21/063 (2013.01); B01J 35/1019 (2013.01); B01J 35/1061 (2013.01); B01J 37/0201 (2013.01); B01J 37/04 (2013.01); B01J 37/088 (2013.01); C07D 301/19 (2013.01);
Abstract

The present invention relates to a preparation method for an olefin epoxidation catalyst, comprising: (1) preparing a titanium-silicon gel; (2) performing pore-enlarging treatment to the titanium-silicon gel by using organic amine or liquid ammonia, and drying, calcinating to obtain a titanium-silicon composite oxide; (3) optionally performing alcohol solution of organic alkali metal salt treatment; and (4) optionally performing gas-phase silanization treatment. The catalyst prepared by the method of the present invention has adjustable variability for pore size, so that the activity thereof for epoxidation reactions of the olefin molecules with different dynamic diameters is higher; the surface acidity of the catalyst can be reduced effectively through two-step modification to the catalyst, so that the catalyst has higher selectivity for epoxidation product.


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