The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 15, 2022

Filed:

Oct. 18, 2017
Applicant:

Versalis S.p.a., San Donato Milanese, IT;

Inventors:

Daniele Delledonne, Oleggio, IT;

Alberto Cesana, Galliate, IT;

Marco Mattachini, Mezzomerico, IT;

Monica Vittoria Pastori, Cuggiono, IT;

Assignee:

Versalis S.P.A., San Donato Milanese, IT;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C01C 1/24 (2006.01); C07C 11/167 (2006.01); C07C 1/24 (2006.01); B01J 37/03 (2006.01); B01J 35/00 (2006.01); B01J 23/10 (2006.01); B01J 29/08 (2006.01); B01J 29/70 (2006.01); B01J 37/00 (2006.01); C07C 29/60 (2006.01); B01J 35/10 (2006.01); B01J 37/08 (2006.01); C07C 33/03 (2006.01); C12P 7/18 (2006.01);
U.S. Cl.
CPC ...
C07C 1/24 (2013.01); B01J 23/10 (2013.01); B01J 29/08 (2013.01); B01J 29/084 (2013.01); B01J 29/7007 (2013.01); B01J 29/7034 (2013.01); B01J 35/0006 (2013.01); B01J 35/1057 (2013.01); B01J 35/1066 (2013.01); B01J 37/0018 (2013.01); B01J 37/031 (2013.01); C07C 29/60 (2013.01); B01J 35/109 (2013.01); B01J 37/08 (2013.01); B01J 2229/37 (2013.01); B01J 2229/42 (2013.01); C07C 11/167 (2013.01); C07C 33/03 (2013.01); C07C 2529/08 (2013.01); C07C 2529/70 (2013.01); C12P 7/18 (2013.01);
Abstract

The present invention relates to a process for producing a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol having a number of carbon atoms greater than or equal to 4, in the presence of a catalytic material comprising at least one crystalline metalosilicate in acid form, preferably a macroporous zeolite, more preferably a zeolite with a FAU, BEA or MTW structure. Preferably, said alkenol having a number of carbon atoms greater than or equal to 4 may be obbtained directly through biosynthetic processes, or through catalytic dehydration processes of at least one diol. When said alkenol is a butenol, said diol is preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, i.e. 1,3-butanediol deriving from biosynthetic processes. When said alkenol is 1,3-butanediol, or bio-1,3-butanediol, the diene obtained with the process according to the present invention is, respectively, 1,3-butadiene, or bio-1,3-butadiene.


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