The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 15, 2022

Filed:

Sep. 29, 2017
Applicants:

Regents of the University of Minnesota, Minneapolis, MN (US);

University of Massachusetts Amherst, Amherst, MA (US);

University of Delaware, Newark, DE (US);

Inventors:

Hong Je Cho, Amherst, MA (US);

Wei Fan, Amherst, MA (US);

Michael Tsapatsis, Edina, MN (US);

Paul J. Dauenhauer, Shoreview, MN (US);

Limin Ren, Minneapolis, MN (US);

Raul Lobo, Newark, DE (US);

Assignees:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/24 (2006.01); B01J 29/70 (2006.01); B01J 29/85 (2006.01); B01J 29/40 (2006.01); B01J 37/28 (2006.01); C07C 2/86 (2006.01); C07C 6/06 (2006.01); C07C 51/42 (2006.01); B01J 35/10 (2006.01); B01J 37/02 (2006.01);
U.S. Cl.
CPC ...
B01J 29/85 (2013.01); B01J 29/40 (2013.01); B01J 29/7007 (2013.01); B01J 35/109 (2013.01); B01J 35/1085 (2013.01); B01J 37/0201 (2013.01); B01J 37/28 (2013.01); C07C 1/24 (2013.01); C07C 2/865 (2013.01); C07C 6/06 (2013.01); C07C 51/42 (2013.01); B01J 2229/18 (2013.01); B01J 2229/183 (2013.01); B01J 2229/186 (2013.01); B01J 2229/37 (2013.01); C07C 2521/04 (2013.01); C07C 2521/06 (2013.01); C07C 2521/08 (2013.01); C07C 2521/10 (2013.01); C07C 2521/12 (2013.01); C07C 2521/18 (2013.01); C07C 2523/10 (2013.01); C07C 2523/20 (2013.01); C07C 2527/167 (2013.01); C07C 2527/18 (2013.01); C07C 2527/188 (2013.01); C07C 2529/08 (2013.01); C07C 2529/40 (2013.01); C07C 2529/70 (2013.01); C07C 2529/82 (2013.01); C07C 2529/85 (2013.01);
Abstract

Methods and phosphorus-containing solid catalysts for catalyzing dehydration of cyclic ethers (e.g., furans, such as 2,5-dimethylfuran) and alcohols (e.g., ethanol and isopropanol). The alcohols and cyclic ethers may be derived from biomass. One example includes a tandem Diels-Alder cycloaddition and dehydration of biomass-derived 2,5-dimethyl-furan and ethylene to renewable p-xylene. The phosphorus-containing solid catalysts are also active and selective for dehydration of alcohols to alkenes.


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