The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 08, 2022

Filed:

May. 05, 2020
Applicant:

Exelus Inc., Fairfield, NJ (US);

Inventors:

Mitrajit Mukherjee, Livingston, NJ (US);

Vamsi M. Vadhri, Kearny, NJ (US);

Narendra Joshi, Jersey City, NJ (US);

Assignee:

Exelus Inc., Fairfield, NJ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/86 (2006.01); C07C 2/58 (2006.01); B01J 29/89 (2006.01); B01J 23/80 (2006.01); B01J 29/70 (2006.01); B01J 29/40 (2006.01); B01J 21/04 (2006.01); B01J 21/08 (2006.01); B01J 29/18 (2006.01); B01J 29/08 (2006.01); B01J 35/10 (2006.01); B01J 8/04 (2006.01); C07C 1/20 (2006.01); C07C 5/373 (2006.01); C10G 29/20 (2006.01); C10G 3/00 (2006.01); B01J 21/12 (2006.01); B01J 35/02 (2006.01);
U.S. Cl.
CPC ...
C07C 2/864 (2013.01); B01J 8/04 (2013.01); B01J 21/04 (2013.01); B01J 21/08 (2013.01); B01J 21/12 (2013.01); B01J 23/80 (2013.01); B01J 29/08 (2013.01); B01J 29/087 (2013.01); B01J 29/18 (2013.01); B01J 29/40 (2013.01); B01J 29/7007 (2013.01); B01J 29/7057 (2013.01); B01J 29/89 (2013.01); B01J 35/023 (2013.01); B01J 35/1019 (2013.01); B01J 35/1023 (2013.01); B01J 35/1057 (2013.01); C07C 1/20 (2013.01); C07C 2/58 (2013.01); C07C 2/865 (2013.01); C07C 5/373 (2013.01); C10G 3/49 (2013.01); C10G 29/205 (2013.01); B01J 2523/00 (2013.01); C07C 2521/04 (2013.01); C07C 2521/06 (2013.01); C07C 2521/08 (2013.01); C07C 2521/12 (2013.01); C07C 2523/755 (2013.01); C07C 2523/80 (2013.01); C07C 2529/08 (2013.01); C07C 2529/18 (2013.01); C07C 2529/40 (2013.01); C07C 2529/89 (2013.01);
Abstract

Methods of simultaneously converting butanes and methanol to olefins over Ti-containing zeolite catalysts are described. The exothermicity of the alcohols to olefins reaction is matched by endothermicity of dehydrogenation reaction of butane(s) to light olefins resulting in a thermo-neutral process. The Ti-containing zeolites provide excellent selectivity to light olefins as well as exceptionally high hydrothermal stability. The coupled reaction may advantageously be conducted in a staged reactor with methanol/DME conversion zones alternating with zones for butane(s) dehydrogenation. The resulting light olefins can then be reacted with iso-butane to produce high-octane alkylate. The net result is a highly efficient and low cost method for converting methanol and butanes to alkylate.


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