The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 06, 2022

Filed:

Jan. 14, 2020
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Mayank Shekhar, Houston, TX (US);

Paul Podsiadlo, Humble, TX (US);

Michel Molinier, Houston, TX (US);

Scott J. Weigel, Allentown, PA (US);

Travis D. Sparks, Deer Park, TX (US);

Jocelyn A. Gilcrest, Mullica Hill, NJ (US);

Joseph E. Gatt, Annandale, NJ (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 38/12 (2006.01); B01J 38/10 (2006.01); B01J 29/40 (2006.01); B01J 29/72 (2006.01); B01J 6/00 (2006.01); C07C 5/22 (2006.01); C07C 6/06 (2006.01); B01J 37/00 (2006.01); B01J 37/20 (2006.01); B01J 37/02 (2006.01); C07C 15/08 (2006.01);
U.S. Cl.
CPC ...
B01J 38/12 (2013.01); B01J 6/001 (2013.01); B01J 29/40 (2013.01); B01J 29/7269 (2013.01); B01J 29/7276 (2013.01); B01J 37/0009 (2013.01); B01J 37/0236 (2013.01); B01J 37/20 (2013.01); B01J 38/10 (2013.01); C07C 5/222 (2013.01); C07C 6/06 (2013.01); C07C 15/08 (2013.01);
Abstract

Methods are provided for activation of catalysts comprising low amounts of a hydrogenation metal, such as low amounts of a Group 8-10 noble metal. The amount of hydrogenation metal on the catalyst can correspond to 0.5 wt % or less (with respect to the weight of the catalyst), or 0.1 wt % or less, or 0.05 wt % or less. Prior to loading a catalyst into a reactor, the corresponding catalyst precursor can be first activated in a hydrogen-containing atmosphere containing 1.0 vppm of CO or less. The thus first-activated catalyst can be transferred to a reactor with optional exposure to oxygen during the transfer, where it can be further activated using a hydrogen-containing atmosphere containing 3.0 vppm of CO or higher, to yield a twice-activated catalyst with high performance. The catalyst can be advantageously a transalkylation catalyst or an isomerization catalyst useful for converting aromatic hydrocarbons.


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