The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 23, 2022

Filed:

Apr. 03, 2019
Applicants:

Dow Global Technologies Llc, Midland, MI (US);

Georgia Tech Research Corporation, Atlanta, GA (US);

Inventors:

Justin T. Vaughn, Medford, MA (US);

Wulin Qiu, Snellville, GA (US);

William J. Koros, Atlanta, GA (US);

Liren Xu, Spring, TX (US);

Mark K. Brayden, Plaquemine, LA (US);

Marcos V. Martinez, Freeport, TX (US);

Assignees:

Dow Global Technologies LLC, Midland, MI (US);

Georgia Tech Resarch Corporation, Atlanta, GA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/22 (2006.01); B01D 67/00 (2006.01); B01D 69/08 (2006.01); B01D 71/02 (2006.01); C01B 3/50 (2006.01);
U.S. Cl.
CPC ...
B01D 53/228 (2013.01); B01D 67/0067 (2013.01); B01D 67/0083 (2013.01); B01D 69/08 (2013.01); B01D 71/021 (2013.01); C01B 3/508 (2013.01); B01D 2053/224 (2013.01);
Abstract

The invention is an improved method of making an improved carbon molecular sieve (CMS) membrane in which a precursor polymer (e.g., polyimide) is pyrolyzed at a pyrolysis temperature to form a CMS membrane that is cooled to ambient temperature (about 40° C. or 30° C. to about 20° C.). The CMS membrane is then reheated to a reheating temperature less than the pyrolysis temperature to form the improved CMS membrane. The improved CMS membranes have shown an improved combination of selectivity and permeance as well as stability for separating hydrogen from gas molecules (e.g., methane, ethane, propane, ethylene, propylene, butane, carbon dioxide, nitrogen, butylene, and combinations thereof).


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