The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 16, 2022

Filed:

Jun. 11, 2019
Applicant:

Ohio State Innovation Foundation, Columbus, OH (US);

Inventors:

Casey Wade, Dublin, OH (US);

Caitlin Bien, Columbus, OH (US);

Zhongzheng Cai, Columbus, OH (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/02 (2006.01); B01J 20/22 (2006.01);
U.S. Cl.
CPC ...
B01D 53/02 (2013.01); B01J 20/226 (2013.01); B01D 2253/204 (2013.01); B01D 2257/302 (2013.01); B01D 2257/404 (2013.01); B01D 2257/504 (2013.01); B01D 2257/7022 (2013.01); B01D 2259/40088 (2013.01);
Abstract

Disclosed are MOFs containing nucleophilic transition metal hydroxide (M-OH) groups. In certain embodiments, these MOFs can include a plurality of metal ions, each coordinated with one or more hydroxide ligands and one or more backbone ligands. In certain embodiments, the MOFs can comprise Kuratowski cluster-based secondary building units (SBUs). These MOFs can exhibit excellent performance for low pressure COcapture via a CO/HCOfixation mechanism in which cooperative inter-cluster hydrogen bonding interactions enhance COcapture performance. Also provided are methods of making MOFs including one or more metal hydroxide moieties, as well as methods of using these MOFs to capture an acidic gas (e.g., CO, SO, NO, or acetylene).


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