The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 19, 2022

Filed:

Feb. 07, 2020
Applicants:

Dow Global Technologies Llc, Midland, MI (US);

Rohm and Haas Company, Collegeville, PA (US);

The Regents of the University of California, Oakland, CA (US);

Inventors:

Jing Ming Ren, Hockessin, DE (US);

Craig Hawker, Santa Barbara, CA (US);

Johannes Willenbacher, Ludwigshafen am Rhein, DE;

Alaina McGrath, Santa Barbara, CA (US);

Benjaporn Narupai, Goleta, CA (US);

David Laitar, Midland, MI (US);

Antony Van Dyk, Blue Bell, PA (US);

Assignees:

DOW GLOBAL TECHNOLOGIES LLC, Midland, MI (US);

ROHM AND HAAS COMPANY, Collegeville, PA (US);

THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, Oakland, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 220/06 (2006.01); C08F 120/06 (2006.01);
U.S. Cl.
CPC ...
C08F 220/06 (2013.01); C08F 120/06 (2013.01); C08F 2410/01 (2013.01); C08F 2438/00 (2013.01);
Abstract

Iodine transfer radical polymerization of an ethylenically unsaturated monomer comprising (meth)acrylic acid, salt thereof, or combination thereof, in the presence of a radical polymerization initiator, an organoiodide, and a solvent, is a useful method for making (meth)acrylic acid polymers. The amounts of components utilized can be 2 to 100 equivalents of acrylic acid and 2 to 100 equivalents of sodium acrylate, both dissolved in water to form a 15 to 50 weight percent solution, based on the total weight of the acrylic acid, sodium acrylate, and water; 0.05 to 1 equivalent of an azo polymerization initiator, 1 equivalent of an organoiodide; and 0 to 3 equivalents of an iodide salt. (Meth)acrylic acid polymer solutions are made by these methods. The (meth)acrylic polymers are useful as dispersants.


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