The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 28, 2022

Filed:

Jul. 08, 2020
Applicant:

Tongji University, Shanghai, CN;

Inventors:

Fengting Li, Shanghai, CN;

Ying Wang, Shanghai, CN;

Tao Feng, Shanghai, CN;

Assignee:

TONGJI UNIVERSITY, Shanghai, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/22 (2006.01); B01J 20/06 (2006.01); B01J 20/30 (2006.01);
U.S. Cl.
CPC ...
B01J 20/226 (2013.01); B01J 20/06 (2013.01); B01J 20/3064 (2013.01); B01J 20/3078 (2013.01); B01J 2220/46 (2013.01);
Abstract

A method for assembling and synthesizing CuO particle-supported porous CuBTC includes the following steps of: 1) dissolving polyvinylpyrrolidone (PVP) in ethanol solution to obtain a PVP-ethanol solution; 2) dissolving copper salt in distilled water, and mixing with trimesic acid, salicylic acid, and the PVP-ethanol solution obtained in step 1) under stirring; and 3) conducting a hydrothermal reaction on the mixed solution obtained in step 2) at 120° C. to obtain CuO particle-supported porous CuBTC. The new method introduces salicylic acid during the synthesis of CuBTC. The salicylic acid, as a ligand precursor, forms a porous CuBTC material through the unsaturated coordination of a ligand under the catalysis of Cu ion. The resulting porous CuBTC supported with ultrafine CuO nanoparticles can adsorb high-energy molecules and exhibit excellent crystallinity, porosity, and stability.


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