The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 14, 2022

Filed:

Mar. 26, 2021
Applicant:

Chevron Phillips Chemical Company Lp, The Woodlands, TX (US);

Inventors:

Steven M. Bischof, Humble, TX (US);

Brooke L. Small, Kingwood, TX (US);

Assignee:

Chevron Phillips Chemical Company, LP, The Woodlands, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 2/32 (2006.01);
U.S. Cl.
CPC ...
C07C 2/32 (2013.01); C07C 2531/14 (2013.01); C07C 2531/22 (2013.01); Y02P 20/52 (2015.11);
Abstract

A process comprising A) continuously introducing into a reaction zone i) ethylene, ii) an iron salt, iii) a pyridine bisimine, iv) an organoaluminum compound, and v) an organic reaction medium, and B) forming an oligomer product in the reaction zone, the reaction zone having i) an iron of the iron salt concentration in a range of 5×10mmol/kg to 5×10mmol/kg, ii) an aluminum of the organoaluminum compound to iron of the iron salt molar ratio in a range of 300:1 to 800:1, ii) an ethylene partial pressure in a range of 750 psig to 1200 psig, iv) an ethylene to organic reaction medium mass ratio in a range of 0.8 to 4.5, v) a temperature in a range of 75° C. to 95° C., and optionally vi) a hydrogen partial pressure of at least 5 psi.


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