The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 26, 2022

Filed:

Apr. 17, 2020
Applicant:

Sion Power Corporation, Tucson, AZ (US);

Inventors:

Yuriy V. Mikhaylik, Tucson, AZ (US);

Chariclea Scordilis-Kelley, Tucson, AZ (US);

Igor P. Kovalev, Vail, AZ (US);

Cathie Burgess, Tucson, AZ (US);

Assignee:

Sion Power Corporation, Tucson, AZ (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 10/0569 (2010.01); H01M 4/1395 (2010.01); H01M 4/134 (2010.01); H01M 10/0566 (2010.01); H01M 4/136 (2010.01); H01M 10/0565 (2010.01); H01M 50/411 (2021.01); H01M 10/0525 (2010.01); H02J 7/00 (2006.01);
U.S. Cl.
CPC ...
H01M 10/0569 (2013.01); H01M 4/134 (2013.01); H01M 4/136 (2013.01); H01M 4/1395 (2013.01); H01M 10/0525 (2013.01); H01M 10/0565 (2013.01); H01M 10/0566 (2013.01); H01M 50/411 (2021.01); H02J 7/0068 (2013.01); H01M 2300/0085 (2013.01); H01M 2300/0094 (2013.01); Y10T 29/49115 (2015.01);
Abstract

Methods and articles relating to separation of electrolyte compositions within lithium batteries are provided. The lithium batteries described herein may include an anode having lithium as the active anode species and a cathode having sulfur as the active cathode species. Suitable electrolytes for the lithium batteries can comprise a heterogeneous electrolyte including a first electrolyte solvent (e.g., dioxolane (DOL)) that partitions towards the anode and is favorable towards the anode (referred to herein as an 'anode-side electrolyte solvent') and a second electrolyte solvent (e.g., 1,2-dimethoxyethane (DME)) that partitions towards the cathode and is favorable towards the cathode (and referred to herein as an 'cathode-side electrolyte solvent'). By separating the electrolyte solvents during operation of the battery such that the anode-side electrolyte solvent is present disproportionately at the anode and the cathode-side electrolyte solvent is present disproportionately at the cathode, the battery can benefit from desirable characteristics of both electrolyte solvents (e.g., relatively low lithium reactivity of the anode-side electrolyte solvent and relatively high polysulfide solubility of the cathode-side electrolyte solvent).


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