The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 19, 2022

Filed:

Apr. 02, 2019
Applicant:

King Fahd University of Petroleum and Minerals, Dhahran, SA;

Inventors:

Tawfik Abdo Saleh Awadh, Dhahran, SA;

Nadeem Baig, Dhahran, SA;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/00 (2006.01); C08F 12/08 (2006.01); B01J 20/20 (2006.01); B01J 20/26 (2006.01); C02F 1/28 (2006.01); C08J 5/04 (2006.01); C08F 283/00 (2006.01); C08F 2/34 (2006.01); C08F 8/00 (2006.01); C08L 51/00 (2006.01); C08L 75/04 (2006.01); C08F 2/48 (2006.01); C02F 103/36 (2006.01);
U.S. Cl.
CPC ...
C08F 12/08 (2013.01); B01J 20/205 (2013.01); B01J 20/262 (2013.01); C02F 1/288 (2013.01); C08F 2/34 (2013.01); C08F 2/48 (2013.01); C08F 8/00 (2013.01); C08F 283/002 (2013.01); C08J 5/042 (2013.01); C08L 51/003 (2013.01); C08L 75/04 (2013.01); C02F 2103/365 (2013.01); C08J 2325/06 (2013.01); C08J 2375/04 (2013.01);
Abstract

Vapor phase polymerization can be used to synthesize a 3D porous network of polystyrene-containing, branched carbon nanofibers on polyurethane(s), optionally using natural light (NL) initiation. NL styrene polymerization in a confined reactor containing CNF-grafted PU can provide a stable porous network. The NL can vaporize the styrene by increasing the reactor temperature and generate styrene radicals. Without CNF, the polymerization on polyurethane (PU) provides a delicate, fragile surface. Radical styrene in vapor phase can interact with CNF to produce polystyrene branches by generating active sites on CNF, while reinforcing the 3D porous structure. After polymerization, the PU surface area increased from 9 to 184 m/g and pore size decreased from 2567 to 10 Å. 3D porous networks of NL-assisted PS branched CNF supported PU can provide a hydrophobic, oleophilic surface with a water contact angle of approx 148±3°, rapidly gravity separating hexane and water without external force.


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