The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 12, 2022

Filed:

Oct. 16, 2018
Applicant:

Institute of Inorganic Chemistry, Cas, Husinec, CZ;

Inventors:

Jan Demel, Vltavou, CZ;

Jan Hynek, Ostrov, CZ;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 20/22 (2006.01); B01J 20/28 (2006.01); C01B 32/50 (2017.01); C08G 83/00 (2006.01); C01B 21/02 (2006.01); C01B 3/00 (2006.01); B01J 20/30 (2006.01);
U.S. Cl.
CPC ...
B01J 20/226 (2013.01); B01J 20/28061 (2013.01); B01J 20/28064 (2013.01); B01J 20/28066 (2013.01); B01J 20/3085 (2013.01); C01B 3/0015 (2013.01); C01B 21/02 (2013.01); C01B 32/50 (2017.08); C08G 83/003 (2013.01);
Abstract

The invention concerns new types of porous coordination polymers (MOF) and a method for their preparation. MOFs have been prepared through synthesis of salts of trivalent cations M, the source of which are aluminium, chromium, iron or yttrium salts, it is advantageous if of chlorides, nitrates or sulphates, with linkers carrying two or more phosphinic groups under presence of solvent. Linkers are phenylene-1,4-bis(R phosphinic acid) (PBPA) and biphenylene-4,4'-bis(R phosphinic acid) (BBPA). For the prepared MOFs, the structure has been tested using x-ray powder diffraction, specific surface and porousness which have been characterised through adsorption isotherm of nitrogen and further the stability of prepared MOFs has been determined using thermogravimetric analysis. All the prepared MOFs have been stable around 400° C. and have contained mesopores or micropores where hydrogen or CO, for example, can be stored.


Find Patent Forward Citations

Loading…