The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 29, 2022

Filed:

Jan. 29, 2020
Applicant:

Colorado State University Research Foundation, Fort Collins, CO (US);

Inventors:

Garret Miyake, Fort Collins, CO (US);

Ryan M. Pearson, Berkeley, CA (US);

Matthew D. Ryan, Berkeley, CA (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08G 61/12 (2006.01);
U.S. Cl.
CPC ...
C08G 61/125 (2013.01); C08G 61/124 (2013.01); C08G 2261/128 (2013.01); C08G 2261/136 (2013.01); C08G 2261/1426 (2013.01); C08G 2261/1432 (2013.01); C08G 2261/3241 (2013.01); C08G 2261/3245 (2013.01); C08G 2261/3324 (2013.01); C08G 2261/418 (2013.01);
Abstract

The present invention provides efficient processes for preparing brush polymers. In general, the process comprises three distinct reaction steps utilizing two separate catalysts. In the first step, the initiating compound comprising norbornene is contacted with a silane in the presence of a catalyst, thereby forming a silated intermediate. This silated intermediate is then contacted with a monomer in the presence of a catalyst via Group Transfer Polymerization (GTP). The resulting compound from GTP is contacted with a ring opening metathesis polymerization (ROMP) catalyst to prepare the brush polymer. Surprisingly, the brush polymers obtained from the above process are accessed in an efficient and rapid GTP methodology as compared to prior methods.


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