The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 22, 2022

Filed:

Sep. 18, 2018
Applicant:

Roehm Gmbh, Darmstadt, DE;

Inventors:

Steffen Krill, Muehltal, DE;

Marcel Treskow, Darmstadt, DE;

Assignee:

Roehm GmbH, Darmstadt, DE;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 67/44 (2006.01); B01J 35/00 (2006.01); B01J 37/02 (2006.01); C07C 67/39 (2006.01); B01J 37/18 (2006.01); B01J 21/04 (2006.01); B01J 21/06 (2006.01); B01J 21/08 (2006.01); B01J 23/52 (2006.01); B01J 23/80 (2006.01); B01J 35/02 (2006.01); B01J 35/10 (2006.01); C07C 69/54 (2006.01);
U.S. Cl.
CPC ...
C07C 67/44 (2013.01); B01J 21/04 (2013.01); B01J 21/063 (2013.01); B01J 21/066 (2013.01); B01J 21/08 (2013.01); B01J 23/52 (2013.01); B01J 23/80 (2013.01); B01J 35/006 (2013.01); B01J 35/008 (2013.01); B01J 35/023 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1061 (2013.01); B01J 37/0201 (2013.01); B01J 37/0236 (2013.01); B01J 37/18 (2013.01); C07C 67/39 (2013.01); C07C 69/54 (2013.01);
Abstract

The present invention relates to a novel process for oxidative esterification, generally for reaction of aldehydes with alcohols in the presence of oxygenous gases directly to give the corresponding ester in the presence of a heterogeneous catalyst, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The new catalyst has titanium dioxide as the main component of the support material. The catalysts are especially notable for high mechanical and chemical stability and for good catalytic performance even over very long periods. The process is an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.


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