The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 01, 2022

Filed:

Nov. 14, 2018
Applicants:

China Petroleum & Chemical Corporation, Beijing, CN;

Dalian Research Institute of Petroleum and Petrochemicals, Sinopec Corp., Liaoning, CN;

Inventors:

Kai Qiao, Liaoning, CN;

Feng Zhou, Liaoning, CN;

Jie Su, Liaoning, CN;

Huixia Ma, Liaoning, CN;

Qingtong Zhai, Liaoning, CN;

Shumei Zhang, Liaoning, CN;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
B01J 23/72 (2006.01); B01J 23/83 (2006.01); B01J 37/03 (2006.01); B01J 37/08 (2006.01); C07C 45/00 (2006.01); B01J 23/889 (2006.01); B01J 23/78 (2006.01); B01J 37/00 (2006.01); B01J 37/18 (2006.01); B01J 31/02 (2006.01); B01J 23/80 (2006.01); B01J 23/86 (2006.01); B01J 37/34 (2006.01); C07C 49/17 (2006.01);
U.S. Cl.
CPC ...
B01J 23/8892 (2013.01); B01J 23/78 (2013.01); B01J 23/80 (2013.01); B01J 23/83 (2013.01); B01J 23/868 (2013.01); B01J 31/0202 (2013.01); B01J 31/0208 (2013.01); B01J 37/0009 (2013.01); B01J 37/031 (2013.01); B01J 37/036 (2013.01); B01J 37/08 (2013.01); B01J 37/18 (2013.01); B01J 37/343 (2013.01); C07C 45/002 (2013.01); B01J 2523/00 (2013.01); C07C 49/17 (2013.01);
Abstract

The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II'). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin.R1-C(═O)—CH(OH)—R2  (II)R1-C(═O)—CH(═O)—R2  (II′) In formulae (II) and (II′), each group is defined as in the description.


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