The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 22, 2022

Filed:

Aug. 04, 2020
Applicant:

Lyondellbasell Acetyls, Llc, Houston, TX (US);

Inventors:

Linn Fang, Houston, TX (US);

Chuc T. Nguyen, La Porte, TX (US);

Assignee:

LyondellBasell Acetyls, LLC, Houston, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 67/54 (2006.01); B01D 3/42 (2006.01); C07C 69/15 (2006.01);
U.S. Cl.
CPC ...
C07C 67/54 (2013.01); B01D 3/4238 (2013.01); C07C 69/15 (2013.01);
Abstract

Purification methods and systems for working up a crude vinyl acetate stream containing vinyl acetate monomer, acetic acid, water, ethyl acetate, and other impurities. Crude vinyl acetate streams are purified with an azeotropic distillation tower using a side draw to remove ethyl acetate and water, and a bottom stream to remove acetic acid from the crude vinyl acetate. The methods and systems move the side draw to a location on the azeotropic distillation tower that maintains a constant water concentration in the bottom product of about 4 to about 15 wt. % and forms a vapor side product. A second distillation tower is used to further purify the vapor side product to obtain water, VAM, ethyl acetate and AA. The system provides easier disposal of ethyl acetate, and cleaner water that can be recycled in the reactor or purification sections of a VAM plant and full recovery of AA.


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