The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 08, 2022

Filed:

Nov. 27, 2017
Applicant:

South China University of Technology, Guangdong, CN;

Inventors:

Kui Shen, Guangdong, CN;

Yingwei Li, Guangdong, CN;

Yonghai Cao, Guangdong, CN;

Junying Chen, Guangdong, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/16 (2006.01); B01J 37/00 (2006.01); B01J 37/02 (2006.01); B01J 37/06 (2006.01); C07D 233/58 (2006.01);
U.S. Cl.
CPC ...
B01J 31/1691 (2013.01); B01J 37/0018 (2013.01); B01J 37/0203 (2013.01); B01J 37/0205 (2013.01); B01J 37/0236 (2013.01); B01J 37/06 (2013.01); C07D 233/58 (2013.01);
Abstract

An ordered macroporous metal-organic framework single crystals and a preparation method therefor. In the method, a three-dimensional structure constructed by polymer microspheres is used as a template; 2-methylimidazole and zinc nitrate, precursors of MOFs, are firstly deposited in the three-dimensional template; the three-dimensional template containing the precursors is soaked in a mixed solution of ammonia water and methanol subsequently, and the three-dimensional template is taken out after crystallization; the three-dimensional template is soaked in an organic solvent to remove the macromolecular three-dimensional template, and the ordered macroporous MOF single crystals is obtained through centrifugal separation. The ordered macroporous MOF single crystals have a basic framework of zeolitic imidazolate framework-8, and structurally include highly-ordered macro-pores whose pore size may be controlled to be between 50 and 2000 nm based on a size of the used template.


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