The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 25, 2022

Filed:

Apr. 25, 2019
Applicant:

Uti Limited Partnership, Calgary, CA;

Inventors:

Jared M. Taylor, Calgary, CA;

Roger K. Mah, Calgary, CA;

George K. H. Shimizu, Calgary, CA;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 3/06 (2006.01); B01J 20/22 (2006.01); B01J 20/28 (2006.01); B01J 20/30 (2006.01);
U.S. Cl.
CPC ...
C07F 3/06 (2013.01); B01J 20/226 (2013.01); B01J 20/2808 (2013.01); B01J 20/28064 (2013.01); B01J 20/3078 (2013.01); B01J 20/3085 (2013.01);
Abstract

Method for making a Zn MOF of formula ZnHtCL, where Ht is 1,2,4-triazolate or a combination of 1,2,4-triazolate and one or more other cycloazocarbyl compound, and CL is oxalate or a combination of oxalate and one or more chelating ligand other than oxalate. More specifically, the Zn MOF is ZnTzOx, where Tz is 1,2,4-triazolate and Ox is oxalate. The method includes reacting 2 molar equivalents of 1,2,4-triazole or the combination with cycloazocarbyl compound with 1 molar equivalent of oxalate or the combination with other chelating ligand and adding 2 molar equivalents of Znto form the Zn MOF. The solvent used can be a lower alcohol or a miscible mixture of water and a lower alcohol. One or both reaction steps are conducted at a temperature less than or equal to 120° C. and can be conducted at room temperature and ambient pressure.


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