The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 11, 2022

Filed:

Oct. 07, 2019
Applicant:

Bioenno Tech Llc, Santa Ana, CA (US);

Inventors:

Zhigang Lin, Santa Ana, CA (US);

Chunhu Tan, Santa Ana, CA (US);

Tianyu Meng, Santa Ana, CA (US);

Shuyi Chen, Santa Ana, CA (US);

Kevin Zanjani, Santa Ana, CA (US);

Assignee:

BIOENNO TECH LLC, Santa Ana, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01M 50/446 (2021.01); H01M 6/18 (2006.01); H01M 10/052 (2010.01); H01M 10/056 (2010.01); C08J 5/18 (2006.01); C08L 71/02 (2006.01); C08K 3/105 (2018.01); C08K 3/22 (2006.01); C08K 5/00 (2006.01);
U.S. Cl.
CPC ...
H01M 50/446 (2021.01); C08J 5/18 (2013.01); H01M 6/181 (2013.01); H01M 6/185 (2013.01); H01M 10/052 (2013.01); H01M 10/056 (2013.01); C08J 2371/02 (2013.01); C08K 3/105 (2018.01); C08K 5/0016 (2013.01); C08K 2003/221 (2013.01); C08K 2003/2227 (2013.01); C08K 2003/2244 (2013.01); C08K 2201/011 (2013.01); C08L 71/02 (2013.01); H01M 2300/0071 (2013.01); H01M 2300/0082 (2013.01); H01M 2300/0091 (2013.01);
Abstract

Ceramic-polymer film includes a polymer matrix, plasticizers, a lithium salt, and a ceramic nanoparticle, LLZO: AlLiLaZrTaOwhere x ranges from 0 to 0.85. The nanoparticles have diameters that range from 20 to 2000 nm and the film has an ionic conductivity of greater than 1×10S/cm (−20° C. to 10° C.) and larger than 1×10S/cm (≥20° C.). Using a combination of selected plasticizers to tune the ionic transport temperature dependence enables the battery based on the ceramic-polymer film to be operable in a wide temperature window (−40° C. to 90° C.). Large size nanocomposite film (area ≥8 cm×6 cm) can be formed on a substrate and the concentration of LLZO nanoparticles decreases in the direction of the substrate to form a concentration gradient over the thickness of the film. This large size film can be employed as a non-flammable, solid-state electrolyte for lithium electrochemical pouch cell and further assembled into battery packs.


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