The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 04, 2022

Filed:

Nov. 27, 2017
Applicant:

Zhejiang University, Hangzhou, CN;

Inventors:

Huabin Xing, Hangzhou, CN;

Zhaoqiang Zhang, Hangzhou, CN;

Qiwei Yang, Hangzhou, CN;

Qilong Ren, Hangzhou, CN;

Zongbi Bao, Hangzhou, CN;

Assignee:

ZHEJIANG UNIVERSITY, Hangzhou, CN;

Attorneys:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 7/11 (2006.01); B01D 53/04 (2006.01); B01J 20/22 (2006.01); B01J 20/282 (2006.01);
U.S. Cl.
CPC ...
C07C 7/11 (2013.01); B01D 53/04 (2013.01); B01J 20/226 (2013.01); B01J 20/282 (2013.01); B01D 2253/204 (2013.01); B01D 2256/24 (2013.01); B01D 2257/7022 (2013.01); B01D 2259/40083 (2013.01); B01D 2259/40086 (2013.01); B01J 2220/56 (2013.01); B01J 2220/58 (2013.01);
Abstract

A method for the separation of C4 olefin mixtures using anion-pillared hybrid porous materials as physical adsorbents is provided. The anion-pillared hybrid porous material was constructed by metal ions (M), organic ligand (L), and inorganic anion (A), forming a three-dimensional structure (A-L-M). C4 olefin mixtures contact with hybrid porous materials in certain ways, then each single C4 olefin monomer can be obtained. The pore size of anion-pillared hybrid porous materials and the spatial configurations of the anions within the pores can be fine-tuned and pre-designed. C4 olefins with different size and shape can be efficiently separated by the anion-pillared hybrid porous materials through shape recognition and size-sieving mechanism.


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