The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jan. 04, 2022

Filed:

May. 24, 2018
Applicant:

Wanhua Chemical Group Co., Ltd., Shandong, CN;

Inventors:

Lei Wang, Shandong, CN;

Tongji Wang, Shandong, CN;

Fei Ye, Shandong, CN;

Lichao Yang, Shandong, CN;

Guangquan Yi, Shandong, CN;

Jiaoying Cui, Shandong, CN;

Naibo Chu, Shandong, CN;

Yuan Li, Shandong, CN;

Weiqi Hua, Shandong, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 37/02 (2006.01); B01J 21/06 (2006.01); B01J 37/08 (2006.01); C07D 301/19 (2006.01); B01J 21/08 (2006.01); C07D 303/04 (2006.01);
U.S. Cl.
CPC ...
B01J 37/0201 (2013.01); B01J 21/063 (2013.01); B01J 37/0236 (2013.01); B01J 37/0238 (2013.01); B01J 37/08 (2013.01); C07D 301/19 (2013.01); B01J 21/08 (2013.01); C07D 303/04 (2013.01);
Abstract

Disclosed in the present invention are a preparation method for an olefin epoxidation catalyst and applications thereof. The method comprises: loading an auxiliary metal salt onto a silica gel carrier, and carrying out a drying treatment to the silica gel carrier; loading a titanium salt (preferably TiCl) onto the silica gel carrier by a chemical vapor deposition method; calcining to obtain a silica gel on which the auxiliary metal oxide and Ti species are loaded; obtaining an catalyst precursor (Ti-MeO—SiOcomposite oxide) by water vapor washing; loading alkyl silicate (preferably tetraethyl orthosilicate) onto the surface of the catalyst precursor by a chemical vapor deposition method and calcining the catalyst precursor to obtain a Ti-MeO—SiOcomposite oxide with the surface coated with a SiOlayer; and carrying out a silylanization treatment to obtain the catalyst. The catalyst can be applied to a chemical process of propylene epoxidation to prepare propylene oxide, and has an average selectivity to PO up to 96.7%, the method of the present invention and the applications thereof have industrial application prospects.


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