The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Nov. 09, 2021

Filed:

Dec. 06, 2017
Applicants:

National Institute of Advanced Industrial Science and Technology, Tokyo, JP;

N.e. Chemcat Corporation, Tokyo, JP;

Inventors:

Junchul Choi, Tsukuba, JP;

Norihisa Fukaya, Tsukuba, JP;

Shunya Onozawa, Tsukuba, JP;

Kazuhiko Sato, Tsukuba, JP;

Hiroyuki Yasuda, Tokyo, JP;

Tomoteru Mizusaki, Tokyo, JP;

Yukio Takagi, Tokyo, JP;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01J 31/22 (2006.01);
U.S. Cl.
CPC ...
B01J 31/2273 (2013.01); B01J 31/22 (2013.01); B01J 2231/4283 (2013.01); B01J 2531/004 (2013.01); B01J 2531/822 (2013.01); B01J 2531/824 (2013.01);
Abstract

An organometallic complex catalyst that makes it possible to obtain a higher yield of a desired product than conventional catalysts in a cross-coupling reaction. The organometallic complex catalyst has a structure represented by formula (1) and is for use in a cross-coupling reaction. In formula (1), M is the coordination center and represents a metal atom such as Pd or an ion thereof. R1, R2, and R3 may be the same or different and are a substituent such as a hydrogen atom. R4, R5, R6, and R7 may be the same or different and are a substituent such as a hydrogen atom. X represents a halogen atom. R8 represents a substituent that has a π bond and 3-20 carbon atoms. With regard to the electron-donating properties of R1-R7 with respect to the coordination center M of the ligand containing R1-R7 that is indicated in formula (2), R1-R7 are arranged in combination such that the TEP value obtained from infrared spectroscopy shifts toward the low frequency side compared to the TEP value of the ligand of formula (2-1).


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