The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Oct. 12, 2021

Filed:

Mar. 18, 2019
Applicant:

Exxonmobil Chemical Patents Inc., Baytown, TX (US);

Inventors:

Sudhin Datta, Houston, TX (US);

Andy H. Tsou, Houston, TX (US);

Ron Walker, Pearland, TX (US);

Hillary L. Passino, Houston, TX (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08L 23/16 (2006.01); C08F 236/04 (2006.01); C08F 210/06 (2006.01); C08F 210/02 (2006.01); C08L 23/14 (2006.01); C08F 236/20 (2006.01); C08F 210/18 (2006.01); C08J 3/21 (2006.01); C08J 3/24 (2006.01);
U.S. Cl.
CPC ...
C08F 236/045 (2013.01); C08F 210/02 (2013.01); C08F 210/06 (2013.01); C08J 3/212 (2013.01); C08J 3/24 (2013.01); C08L 23/142 (2013.01); C08L 23/16 (2013.01); C08F 210/18 (2013.01); C08F 236/20 (2013.01); C08F 2500/03 (2013.01); C08F 2500/12 (2013.01); C08F 2500/17 (2013.01); C08F 2500/21 (2013.01); C08F 2500/24 (2013.01); C08L 2205/025 (2013.01); C08L 2205/03 (2013.01); C08L 2205/08 (2013.01); C08L 2207/02 (2013.01); C08L 2207/10 (2013.01); C08L 2312/00 (2013.01); C08L 2312/02 (2013.01);
Abstract

Disclosed is the preparation of compatibilized thermoplastic vulcanizates with reduced crosslinked rubber dispersion sizes and dispersity. A cross-linkable ethylene-propylene-diene terpolymer with majority propylene (PEDM) is used to compatibilize a plastic and rubber blend of a polypropylene (PP) and an ethylene-propylene-diene terpolymer rubber, where the propylene content is less than 50 wt % (EPDM), in dynamic vulcanization and preparation of PP/EPDM thermoplastic vulcanizates. The resulting PP/EPDM thermoplastic vulcanizates typically exhibit a weight average equivalent dispersion diameter of less than 3 microns and a particle size polydispersity index (PSDI), or weight average over number average dispersion diameter, of less than 5. This reduction in crosslinked rubber dispersion size in a PP/EPDM TPV by using PEDM compatibilizers enhances the toughness of the vulcanizate product by raising both elongation to break and break stress.


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