The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 28, 2021

Filed:

May. 13, 2019
Applicant:

The United States of America, As Represented BY the Secretary of the Navy, Arlington, VA (US);

Inventor:

Heather A. Meylemans, Camarillo, CA (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C25B 3/25 (2021.01); C07F 15/06 (2006.01); C10L 1/04 (2006.01); B01J 19/12 (2006.01); C10L 1/02 (2006.01); C07F 1/08 (2006.01); C25B 11/075 (2021.01);
U.S. Cl.
CPC ...
C07F 15/065 (2013.01); B01J 19/127 (2013.01); C07F 1/08 (2013.01); C10L 1/02 (2013.01); C10L 1/04 (2013.01); C25B 3/25 (2021.01); C25B 11/075 (2021.01); C10L 2290/38 (2013.01);
Abstract

A series of 2,2'-dipyridyl ketone (DPK) containing metal complexes have been synthesized with metals including Mn, Fe, Co, Ni, Cu, Ru, Pd, and Pt. These complexes have one, two or three DPK ligands chelated to the metal center. In addition to the DPK ligands the complexes can comprise halogen ligands that can easily exchange with carbon dioxide to allow for reduction to small molecules such as methanol or oxalate. Initial electrochemical measurements show a reversible binding of carbon dioxide to the metal catalyst.


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