The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 28, 2021

Filed:

May. 03, 2019
Applicant:

Dow Technology Investments Llc, Midland, MI (US);

Inventors:

Michael A. Brammer, Freeport, TX (US);

Michael C. Becker, Hewitt, TX (US);

William N. Felsted, II, Lake Jackson, TX (US);

Assignee:

Dow Technology Investments LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 45/50 (2006.01); B01J 31/00 (2006.01); B01J 31/24 (2006.01);
U.S. Cl.
CPC ...
C07C 45/505 (2013.01); B01J 31/2409 (2013.01); B01J 2231/321 (2013.01); B01J 2531/004 (2013.01); B01J 2531/822 (2013.01);
Abstract

The present invention relates to methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in a hydroformylation process. In one aspect, a method comprises (a) contacting an olefin with carbon monoxide, hydrogen and a catalyst, the catalyst comprising (A) a transition metal, (B) a tetraphosphine having the structure described herein, and, optionally, (C) a monophosphine having the structure described herein, the contacting conducted in one or more reaction zones and at hydroformylation conditions; and (b) adding additional monophosphine having the structure described herein to a reaction zone.


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