The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 28, 2021

Filed:

Nov. 30, 2016
Applicants:

Dow Global Technologies Llc, Midland, MI (US);

Georgia Tech Research Corporation, Atlanta, GA (US);

Inventors:

John Hessler, Ellsworth, ME (US);

William J. Koros, Atlanta, GA (US);

Liren Xu, Pearland, TX (US);

Mark K. Brayden, Baton Rouge, LA (US);

Marcos V. Martinez, Rosharon, TX (US);

Assignee:

Dow Global Technologies LLC, Midland, MI (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 53/22 (2006.01); B01D 71/02 (2006.01); B01D 67/00 (2006.01); B01D 71/64 (2006.01); B01D 69/08 (2006.01);
U.S. Cl.
CPC ...
B01D 71/021 (2013.01); B01D 53/22 (2013.01); B01D 53/228 (2013.01); B01D 67/0002 (2013.01); B01D 67/0067 (2013.01); B01D 67/0081 (2013.01); B01D 67/0083 (2013.01); B01D 69/08 (2013.01); B01D 71/028 (2013.01); B01D 71/64 (2013.01); B01D 69/088 (2013.01); B01D 2256/10 (2013.01); B01D 2256/24 (2013.01); B01D 2257/104 (2013.01); B01D 2257/7022 (2013.01); B01D 2321/32 (2013.01); Y02C 20/20 (2013.01);
Abstract

The invention is an improved method of making a carbon molecular sieve (CMS) membrane in which a precursor polymer is pyrolyzed to form a carbon molecular sieve membrane that is then exposed to a conditioning atmosphere comprised of a target permeate gas molecule such as ethylene when the membrane is desired to separate it from a light hydrocarbon gas stream. The exposure to the ethylene desirably occurs prior to the CMS permeance and selectivity combination substantially changing (e.g., within 5 days) of cooling from the pyrolyzing temperature. The CMS membranes have shown an improved combination of selectivity and permeance as well as stability and are useful to separate gases in gas streams such methane from natural gas, oxygen from air and ethylene or propylene from light hydrocarbon streams.


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