The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Sep. 14, 2021

Filed:

Jun. 05, 2018
Applicant:

Duke University, Durham, NC (US);

Inventors:

Michael Therien, Durham, NC (US);

Ting Jiang, Durham, NC (US);

Nicholas Polizzi, Durham, NC (US);

Jeffrey Rawson, Durham, NC (US);

Assignee:

DUKE UNIVERSITY, Durham, NC (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07F 15/00 (2006.01); B01J 31/18 (2006.01); B01J 35/00 (2006.01);
U.S. Cl.
CPC ...
C07F 15/0053 (2013.01); B01J 31/183 (2013.01); B01J 31/1815 (2013.01); B01J 35/004 (2013.01); B01J 2231/70 (2013.01); B01J 2531/025 (2013.01); B01J 2531/0216 (2013.01); B01J 2531/0244 (2013.01); B01J 2531/26 (2013.01); B01J 2531/821 (2013.01); B01J 2540/225 (2013.01);
Abstract

High-potential photo-oxidants are provided with a supermolecule structure at least including a conjugated macrocycle linked to a metal complex. The conjugated macrocycle is electron-accepting relative to hydrogen or bears electron withdrawing substituents such as fluoroalkyl, fluoroaryl, fluoro, halo, cyano, or nitro. The metal complex is also electron-accepting relative to hydrogen or bears electron withdrawing substituents such as fluoroalkyl, fluoroaryl, fluoro, halo, cyano, or nitro. The linker can be thynyl, vinyl, thiophenyl, diethynylaryl, divinylaryl, diethynyl(unsaturated heterocycloalkenyl), divinyl(unsaturated heterocycloalkenyl), diethynyl(unsaturated heterocycloalkynyl), or divynyl(unsaturated heterocycloalkynyl). A specific implementation is an ethyne-bridged eDef-Rutpy-(porphinato)Zn(II) (eDef-RuPZn) supermolecule.


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