The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 10, 2021

Filed:

Sep. 01, 2017
Applicant:

Haldor Topsøe A/s, Kgs. Lyngby, DK;

Inventors:

Niels Christian Schjødt, Hvalsø, DK;

Søren Dahl, Hillerød, DK;

Jesper Nerlov, Værløse, DK;

Assignee:

HALDOR TOPSØE A/S, Kgs. Lyngby, DK;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
H01L 31/032 (2006.01); C01B 19/00 (2006.01); H01L 21/02 (2006.01); C01G 19/00 (2006.01);
U.S. Cl.
CPC ...
H01L 21/02535 (2013.01); C01B 19/002 (2013.01); C01G 19/006 (2013.01); H01L 31/0326 (2013.01); C01P 2002/77 (2013.01); C01P 2004/62 (2013.01); C01P 2004/64 (2013.01); C01P 2006/40 (2013.01);
Abstract

A method of producing a kesterite material of CZTS, CZTSe or CZTSSe type, including the steps of: a) preparing an acidic solution by dissolving copper and zinc salts in water in desired molar ratio, b) preparing a basic solution by dissolving an alkali metal stannate together with an alkali metal carbonate or an alkali metal hydrogen carbonate or an alkali metal hydroxide or a combination thereof, and optionally with an alkali metal selenate or an alkali metal selenite or a mixture thereof, c) carrying out a precipitation reaction by mixing the acidic and the basic solution, d) drying the precipitate thereby providing a precursor for the kesterite material, and e) sulfurizing the precursor of step d to provide the kesterite material. Also, a precursor for a kesterite material of CZTS, CZTSe or CZTSSe type.


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