The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 03, 2021

Filed:

Jul. 19, 2019
Applicants:

International Business Machines Corporation, Armonk, NY (US);

Ulvac, Inc., Kanagawa, JP;

Inventors:

John Rozen, Hastings on Hudson, NY (US);

Martin Michael Frank, Dobbs Ferry, NY (US);

Yohei Ogawa, White Plains, NY (US);

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
H01L 21/02 (2006.01); H01L 21/28 (2006.01); H01L 45/00 (2006.01); C23C 16/40 (2006.01); C23C 16/455 (2006.01); H01L 29/51 (2006.01);
U.S. Cl.
CPC ...
H01L 21/0228 (2013.01); C23C 16/405 (2013.01); C23C 16/45527 (2013.01); H01L 21/02244 (2013.01); H01L 21/02255 (2013.01); H01L 29/40114 (2019.08); H01L 45/1616 (2013.01); H01L 45/1633 (2013.01); H01L 29/517 (2013.01); H01L 45/146 (2013.01);
Abstract

Embodiments of the present invention are directed to forming a sub-stoichiometric metal-oxide film using a modified atomic layer deposition (ALD) process. In a non-limiting embodiment of the invention, a first precursor and a second precursor are selected. The first precursor can include a metal and a first ligand. The second precursor can include the same metal and a second ligand. A substrate can be exposed to the first precursor during a first pulse of an ALD cycle. The substrate can be exposed to the second precursor during a second pulse of the ALD cycle. The second pulse can occur directly after the first pulse without an intervening thermal oxidant. The substrate can be exposed to the thermal oxidant during a third pulse of the ALD cycle.


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