The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 03, 2021

Filed:

Apr. 12, 2019
Applicant:

Gevo, Inc., Englewood, CO (US);

Inventors:

Jonathan O. Smith, Highlands Ranch, CO (US);

Madeline Sjodin, Denver, CO (US);

Austin Vaillancourt, Denver, CO (US);

Paul Starkey, Denver, CO (US);

Steve Donen, Chanhassen, MN (US);

Michelle Shebowich, Denver, CO (US);

Assignee:

GEVO, INC., Englewood, CO (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C10G 50/00 (2006.01); B01J 21/06 (2006.01); B01J 29/40 (2006.01); B01J 29/65 (2006.01); C07C 2/08 (2006.01); C07C 2/04 (2006.01); C07C 2/06 (2006.01); C07C 2/10 (2006.01); C07C 2/02 (2006.01);
U.S. Cl.
CPC ...
C10G 50/00 (2013.01); B01J 21/066 (2013.01); B01J 29/405 (2013.01); B01J 29/65 (2013.01); C07C 2/04 (2013.01); C07C 2/06 (2013.01); C07C 2/08 (2013.01); C07C 2/10 (2013.01); C07C 2/02 (2013.01); C10G 2300/1088 (2013.01); C10G 2400/04 (2013.01); C10G 2400/08 (2013.01);
Abstract

The present disclosure provides methods and materials for oligomerization of lower olefins (e.g., C-C) to transportations fuels including diesel and/or jet fuel. The oligomerization employs, in certain embodiments, tungstated zirconium catalysts. Surprisingly, the oligomerizations proceed smoothly in high yields and exhibit little to no sensitivity to the presence of significant amounts of oxygenates (e.g., water, lower alcohols such as C-Calcohols) in the feed stream. Accordingly, the present disclosure is uniquely suited to the production of fuels derived from bio-based alcohols, wherein olefins produced from such bio-based alcohols typically contain high levels of oxygenates.


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