The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Aug. 03, 2021

Filed:

Jun. 20, 2018
Applicant:

Archer Daniels Midland Company, Decatur, IL (US);

Inventors:

Pam Anklam, Lovington, IL (US);

William Chris Hoffman, Decatur, IL (US);

Stephen J. Howard, Sherman, IL (US);

Alexandra Sanborn, Lincoln, IL (US);

Mitchell Schultz, Mt. Zion, IL (US);

John G. Soper, Mt. Zion, IL (US);

Assignee:

ARCHER DANIELS MIDLAND COMPANY, Decatur, IL (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07D 307/68 (2006.01); B01D 15/18 (2006.01); B01D 15/36 (2006.01);
U.S. Cl.
CPC ...
C07D 307/68 (2013.01); B01D 15/1821 (2013.01); B01D 15/364 (2013.01); B01D 2215/023 (2013.01);
Abstract

A process is provided for making esters of FDCA, in which an aqueous feed comprising glucaric acid is first reacted with a high boiling first alcohol in the presence of an acid catalyst and with removing water during the reaction, to form a first product mixture comprising a first ester of FDCA and the high boiling first alcohol, then unreacted high boiling first alcohol is removed from the first product mixture. The first ester of FDCA and the high boiling first alcohol is then transesterified with a lower boiling second alcohol selected from the group consisting of methanol, ethanol, isopropanol and n-propanol, to form a second product mixture comprising a second ester of FDCA with the lower boiling second alcohol, and the second ester of FDCA with the lower boiling second alcohol is recovered.


Find Patent Forward Citations

Loading…