The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 27, 2021

Filed:

Apr. 03, 2019
Applicant:

Qingdao University, Qingdao, CN;

Inventors:

Hui Jin, Qingdao, CN;

Rijun Gui, Qingdao, CN;

Yujiao Sun, Qingdao, CN;

Xiaowen Jiang, Qingdao, CN;

Zejun Sun, Qingdao, CN;

Assignee:

QINGDAO UNIVERSITY, Qingdao, CN;

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
G01N 33/553 (2006.01); G01N 33/543 (2006.01); C09K 11/65 (2006.01); G01N 21/64 (2006.01); G01N 27/327 (2006.01); G01N 33/552 (2006.01); B82Y 30/00 (2011.01); B82Y 35/00 (2011.01); B82Y 40/00 (2011.01); B82Y 20/00 (2011.01);
U.S. Cl.
CPC ...
G01N 33/5438 (2013.01); C09K 11/65 (2013.01); G01N 21/6428 (2013.01); G01N 27/3277 (2013.01); G01N 33/54346 (2013.01); G01N 33/552 (2013.01); G01N 33/553 (2013.01); B82Y 20/00 (2013.01); B82Y 30/00 (2013.01); B82Y 35/00 (2013.01); B82Y 40/00 (2013.01); C12Q 2563/107 (2013.01); C12Q 2563/155 (2013.01); C12Q 2565/519 (2013.01); C12Q 2565/607 (2013.01); G01N 2021/6439 (2013.01);
Abstract

A method for preparing a nanohybrid used for ratiometric fluorescence and ratiometric electrochemical sensing simultaneously is provided. Surface-aminated (—NH) SiOnanospheres encapsulating an electroactive material A or B are prepared and conjugated with surface-carboxylated (—COOH) carbon dots (CDs) or gold nanoclusters (AuNCs) to prepare a conjugate, and the conjugate is conjugated with a DNA aptamer terminated with —NH. Ions or biomolecules are added to two types of DNA-conjugate dispersions, and ratiometric florescence sensing is realized by fitting the linear relationship between ratiometric fluorescent peak intensity I/Iand a specific ion concentration or a specific biomolecule concentration. A-SiO@CDs-DNA is attached to the surface of a gold electrode based on a DNA terminal —SH and Au—S bonding; B—SiO@AuNCs-DNA and ions or biomolecules are added, and ratiometric electrochemical sensing is realized by fitting the linear relationship between the specific ion concentration or the specific biomolecule concentration and the ratiometric current peak intensity I/I.


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