The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 13, 2021

Filed:

Oct. 04, 2017
Applicant:

Shell Oil Company, Houston, TX (US);

Inventors:

Hong-Xin Li, Lansdale, PA (US);

Gisela Sabater Pujadas, Amsterdam, NL;

Ingrid Maria Van Vegchel, Amsterdam, NL;

Yuriy Yanson, Amsterdam, NL;

Assignee:

Shell Oil Company, Houston, TX (US);

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C07C 4/18 (2006.01); B01J 29/44 (2006.01); B01J 35/02 (2006.01); B01J 37/02 (2006.01); C07C 5/27 (2006.01); B01J 37/04 (2006.01); B01J 23/62 (2006.01); B01J 29/80 (2006.01); B01J 35/00 (2006.01); B01J 29/40 (2006.01); B01J 35/10 (2006.01); B01J 37/00 (2006.01); B01J 37/08 (2006.01); C01B 39/38 (2006.01);
U.S. Cl.
CPC ...
B01J 29/44 (2013.01); B01J 23/626 (2013.01); B01J 29/40 (2013.01); B01J 29/80 (2013.01); B01J 35/002 (2013.01); B01J 35/0006 (2013.01); B01J 35/023 (2013.01); B01J 35/1014 (2013.01); B01J 35/1019 (2013.01); B01J 35/1038 (2013.01); B01J 37/0018 (2013.01); B01J 37/0201 (2013.01); B01J 37/0236 (2013.01); B01J 37/04 (2013.01); B01J 37/08 (2013.01); C01B 39/38 (2013.01); C07C 4/18 (2013.01); C07C 5/2708 (2013.01); B01J 2229/16 (2013.01); B01J 2229/37 (2013.01); C01P 2002/60 (2013.01); C01P 2006/12 (2013.01); C01P 2006/14 (2013.01); C07C 2529/44 (2013.01); Y02P 20/52 (2015.11);
Abstract

Process for dealkylation of alkylaromatic compounds which process comprises contacting an alkylaromatic feedstock with i) a first catalyst comprising a) a carrier comprising of from 20 to 70 wt. % of refractory oxide binder and of from 30 to 80 wt. % of dealuminated ZSM-5 having a crystallite size of from 500 to 10,000 nm and a silica to alumina molar ratio (SAR) of from 20 to 100; b) of from 0.001 to 5 wt. % metal chosen from the group consisting of Groups 6, 9 and 10; and optionally c) up to 0.5 wt. % of a Group 14 metal, and ii) a subsequent catalyst comprising a) a carrier comprising of from 20 to 70 wt. % of refractory oxide binder and of from 30 to 80 wt. % of ZSM-5 having a crystallite size of from 3 to 100 nm and a SAR of from 20 to 200; b) of from 0.001 to 5 wt. % of metal chosen from the group consisting of Groups 6, 9 and 10; and optionally c) up to 0.5 wt. % of a Group 14 metal.


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