The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jul. 06, 2021

Filed:

Mar. 07, 2018
Applicant:

California Institute of Technology, Pasadena, CA (US);

Inventors:

Robert H Grubbs, South Pasadena, CA (US);

Tzu-Pin Lin, Pasadena, CA (US);

Alice Chang, Los Angeles, CA (US);

Hsiang-Yun Chen, Pasadena, CA (US);

Christopher M Bates, Santa Barbara, CA (US);

Assignee:
Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
C08G 81/00 (2006.01); C08G 81/02 (2006.01); C08F 285/00 (2006.01); C08F 287/00 (2006.01); C08G 61/08 (2006.01); C08F 290/04 (2006.01); C08F 290/06 (2006.01); C08F 290/02 (2006.01); C08F 267/10 (2006.01); B82Y 40/00 (2011.01); C08F 293/00 (2006.01);
U.S. Cl.
CPC ...
C08G 81/021 (2013.01); C08F 285/00 (2013.01); C08F 287/00 (2013.01); C08F 290/02 (2013.01); C08F 290/04 (2013.01); C08F 290/06 (2013.01); C08G 61/08 (2013.01); B82Y 40/00 (2013.01); C08F 267/10 (2013.01); C08F 290/042 (2013.01); C08F 290/044 (2013.01); C08F 290/046 (2013.01); C08F 290/048 (2013.01); C08F 290/061 (2013.01); C08F 290/062 (2013.01); C08F 290/064 (2013.01); C08F 290/065 (2013.01); C08F 290/067 (2013.01); C08F 290/068 (2013.01); C08F 293/00 (2013.01); C08F 293/005 (2013.01); C08F 2500/09 (2013.01); C08G 2261/126 (2013.01); C08G 2261/128 (2013.01); C08G 2261/136 (2013.01); C08G 2261/144 (2013.01); C08G 2261/148 (2013.01); C08G 2261/149 (2013.01); C08G 2261/1424 (2013.01); C08G 2261/1426 (2013.01); C08G 2261/1428 (2013.01); C08G 2261/418 (2013.01); C08G 2261/722 (2013.01);
Abstract

In an aspect, a method of synthesizing a graft copolymer comprises the steps of: copolymerizing a first macromonomer and a first reactive diluent; wherein said first macromonomer comprises a first backbone precursor directly or indirectly covalently linked to a first polymer side chain group; wherein said reactive diluent is provided in the presence of the first macromonomer at an amount selected so as to result in formation said graft copolymer having a first backbone incorporating said diluent and said first macromonomer in a first polymer block characterized by a preselected first graft density or a preselected first graft distribution of said first macromonomer. In some embodiments of this aspect, said preselected first graft density is any value selected from the range of 0.05 to 0.75. In some methods, the composition and amount of said diluent is selected to provide both a first preselected first graft density and a first preselected first graft distribution.


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