The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 22, 2021

Filed:

Jan. 30, 2018
Applicant:

Massachusetts Institute of Technology, Cambridge, MA (US);

Inventors:

Jeremiah A. Johnson, Boston, MA (US);

Mao Chen, Boston, MA (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 2/46 (2006.01); C08F 2/50 (2006.01); C08G 61/04 (2006.01); C08F 2/38 (2006.01); C08F 4/40 (2006.01); C08F 293/00 (2006.01);
U.S. Cl.
CPC ...
C08F 2/50 (2013.01); C08F 2/38 (2013.01); C08F 4/40 (2013.01); C08F 293/005 (2013.01); C08F 2438/01 (2013.01); C08F 2438/03 (2013.01);
Abstract

Disclosed are methods, compositions, kits, and reagents to prepare compounds (e.g. polymers and small molecules) via radical reactions by utilizing thermoresponsive and photoresponsive gels. This invention discloses the preparation of polymers via controlled radical polymerizations from an iniferter or initiator, one or more reactant monomer, and a thermoresponsive and photoresponsive gel. Embodiments of the invention show that the polymerization is reversibly activated and/or deactivated by controlling one or more of the following external control stimuli: temperature, light, and catalyst presence. This invention also relates the preparation of Gel-PTH, a heterogeneous thermoresponsive and photoresponsive gel.


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