The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 22, 2021

Filed:

May. 09, 2019
Applicant:

Ut-battelle, Llc, Oak Ridge, TN (US);

Inventors:

Derek Brigham, Carlsbad, NM (US);

Laetitia Delmau, Oak Ridge, TN (US);

David DePaoli, Knoxville, TN (US);

Assignee:

UT-Battelle, LLC, Oak Ridge, TN (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
B01D 11/02 (2006.01); C22B 59/00 (2006.01); C07C 235/04 (2006.01);
U.S. Cl.
CPC ...
B01D 11/0288 (2013.01); B01D 11/0292 (2013.01); C07C 235/04 (2013.01); C22B 59/00 (2013.01); B01D 2257/60 (2013.01);
Abstract

A method for extracting rare earth metals (e.g., lanthanides and/or actinides) from aqueous solution, the method comprising: (i) acidifying an aqueous solution containing said rare earth metals with sulfuric acid to result in an acidified aqueous solution containing 1-12 M concentration of sulfuric acid; and (ii) contacting the acidified aqueous solution with an aqueous-insoluble hydrophobic solution comprising a rare earth extractant molecule dissolved in an aqueous-insoluble hydrophobic solvent to result in extraction of one or more of the rare earth metals into the aqueous hydrophobic solution, wherein the rare earth extractant molecule has the following structure: wherein R, R, R, and Rare independently selected from hydrocarbon groups containing 1-20 carbon atoms, provided that the total carbon atoms in R, R, R, and Ris at least 12; and Rand Rare independently selected from hydrogen atom and hydrocarbon groups containing 1-3 carbon atoms.


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