The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Jun. 08, 2021

Filed:

Jan. 12, 2017
Applicant:

Basf SE, Ludwigshafen am Rhein, DE;

Inventors:

Viktor Ladnak, Ludwigshafen, DE;

Silvia Tauro, Ludwigshafen, DE;

Kerstin Heinen, Ludwigshafen, DE;

Kai Thiele, Antwerp, BE;

Klaus-Peter Metzner;

Torsten Mattke, Ludwigshafen, DE;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 209/78 (2006.01); C07C 209/88 (2006.01); B01D 3/14 (2006.01);
U.S. Cl.
CPC ...
C07C 209/78 (2013.01); B01D 3/141 (2013.01); B01D 3/143 (2013.01); C07C 209/88 (2013.01); C07B 2200/07 (2013.01);
Abstract

A process for preparing an aromatic polyamine mixture including 4,4'-methylenedi(phenylamine) and higher homologues of MDA is provided. The process includes steps of (i) reaction of aniline with formaldehyde by means of an acid catalyst to form a crude product mixture (I), (ii) neutralization of the crude product mixture (I) and removal of the salts formed; (iii) isolation of aniline; (iv) distillation of the resulting crude product mixture so as to separate off (iv-1) a mixture (II) of MDA isomers (II-1) containing from 8 to 20% by weight of 4,4′-methylenedi(phenylamine) and not more than 0.3% by weight of secondary components (II-2) and (iv-2) a low boiler mixture of at least 55% by weight of secondary components (II-2) and MDA isomers (II-1); and (v) recirculation of the mixture (II).


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