The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 25, 2021

Filed:

Sep. 28, 2017
Applicant:

W. R. Grace & Co.—conn., Columbia, MD (US);

Inventors:

Michael J. Elder, Baltimore, MD (US);

Ronald A. Epstein, Montclair, NJ (US);

Timothy A. Boyer, Eldersburg, MD (US);

Courtney S. Spain, Laurel, MD (US);

Michael S. Miller, Catonsville, MD (US);

Assignee:

W.R. Grace & Co.—Conn., Columbia, MD (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08F 4/649 (2006.01); C08F 4/659 (2006.01); C08F 210/02 (2006.01); C08F 210/06 (2006.01); C08F 10/06 (2006.01); C08F 4/651 (2006.01); C08F 4/654 (2006.01); C08F 110/06 (2006.01); C08F 4/646 (2006.01);
U.S. Cl.
CPC ...
C08F 4/6494 (2013.01); C08F 4/651 (2013.01); C08F 4/654 (2013.01); C08F 4/6543 (2013.01); C08F 4/65916 (2013.01); C08F 10/06 (2013.01); C08F 110/06 (2013.01); C08F 210/02 (2013.01); C08F 210/06 (2013.01); C08F 4/6465 (2013.01); C08F 2500/12 (2013.01); Y02P 20/52 (2015.11);
Abstract

A phthalate-free procatalyst composition is disclosed for olefin polymerization that exhibits excellent polymerization activity and response to hydrogen, and can produce a polyolefin exhibiting high stereoregularity, high melt flow rate, and desirable molecular weight distribution. The method for producing the procatalyst composition includes reaction of a magnesium support precursor with a tetravalent titanium halide and a combination of different internal electron donors. The first internal electron donor may comprise one or more substituted phenylene aromatic diester and the second internal electron donor may comprise a polyether, preferably a 1,3-diether. In one embodiment, the support precursor comprises a spherical spray crystalized MgCl-EtOH adduct.


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