The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 25, 2021

Filed:

Jun. 25, 2018
Applicant:

Zhejiang Quhua Fluor-chemistry CO Ltd, Zhejiang, CN;

Inventors:

Jiangyong Hong, Zhejiang, CN;

Bo Yang, Zhejiang, CN;

Hao Ouyang, Zhejiang, CN;

Yan Zhang, Zhejiang, CN;

Yang Zhao, Zhejiang, CN;

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 17/20 (2006.01); B01J 23/26 (2006.01); B01J 23/10 (2006.01); B01J 23/08 (2006.01); C07C 21/18 (2006.01);
U.S. Cl.
CPC ...
C07C 17/206 (2013.01); B01J 23/08 (2013.01); B01J 23/10 (2013.01); B01J 23/26 (2013.01); C07C 21/18 (2013.01);
Abstract

Disclosed is a method for co-producing 2,3,3,3-tetrafluoropropene and trans-1,3,3,3-tetrafluoropropene, comprising the following steps: preheating a mixture of 1,1,1,2,2-pentachloropropane and 1,1,1,3,3-pentachloropropane together with anhydrous hydrogen fluoride and simultaneously introducing into a first reactor to react in the presence of a catalyst LaO—CrOto obtain a first reactor product; directly introducing the first reactor product into a second reactor without separation, and carrying out a catalytic fluorination reaction in the presence of a catalyst GaO—YO—CrOto obtain a second reactor product; and separating the second reactor product to obtain the products of 2,3,3,3-tetrafluoropropene and trans-1,3,3,3-tetrafluoropropene. The invention has such advantages that the process is simple and less equipment investment is required; used catalysts have good activity, high selectivity and long total life; and the ratio of the two products can be flexibly adjusted according to market demands.


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