The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
May. 18, 2021

Filed:

Jan. 20, 2016
Applicants:

Umicore, Brussels, BE;

Umicore Korea Ltd., Chungnam, KR;

Inventors:

Xin Xia, Cheonan, KR;

Jens Paulsen, Daejeon, KR;

JiHye Kim, Cheonan, KR;

Song-Yi Han, Daejeon, KR;

Assignees:

Umicore, Brussels, BE;

Umicore Korea Ltd., Chungnam, KR;

Attorney:
Primary Examiner:
Assistant Examiner:
Int. Cl.
CPC ...
H01M 4/36 (2006.01); H01M 4/131 (2010.01); H01M 4/505 (2010.01); H01M 4/525 (2010.01); H01M 10/0525 (2010.01); H01M 4/04 (2006.01); H01M 4/62 (2006.01); H01M 4/485 (2010.01); C01G 53/00 (2006.01);
U.S. Cl.
CPC ...
H01M 4/366 (2013.01); C01G 53/52 (2013.01); C01G 53/66 (2013.01); H01M 4/0471 (2013.01); H01M 4/131 (2013.01); H01M 4/485 (2013.01); H01M 4/505 (2013.01); H01M 4/525 (2013.01); H01M 4/62 (2013.01); H01M 10/0525 (2013.01); C01P 2006/40 (2013.01); H01M 2220/20 (2013.01); H01M 2220/30 (2013.01); Y02T 10/70 (2013.01);
Abstract

A lithium metal oxide powder for a cathode material in a rechargeable battery, consisting of a core and a surface layer, the surface layer being delimited by an outer and an inner interface, the inner interface being in contact with the core, the core having a layered crystal structure comprising the elements Li, M and oxygen, wherein M has the formula M=(Ni(NiMn)Co)A, with 0.15≤x≤0.30, 0.20≤z≤0.55, x+y+z=1 and 0<k≤0.1, wherein the Li content is stoichiometrically controlled with a molar ratio 0.95≤Li:M≤1.10; wherein A is at least one dopant and comprises Al; wherein the core has an Al content of 0.3-3 mol % and a F content of less than 0.05 mol %; and wherein the surface layer has an Al content that increases continuously from the Al content of the core at the inner interface to at least 10 mol % at the outer interface, and a F content that increases continuously from less than 0.05 mol % at the inner interface to at least 3 mol % at the outer interface, the Al and F contents in the surface layer being determined by XPS. The surface layer may also have a Mn content that decreases continuously from the Mn content of the core at the inner interface, to less than 50% of the Mn content of the core at the outer interface.


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