The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 13, 2021

Filed:

Feb. 07, 2018
Applicant:

Chevron U.s.a. Inc., San Ramon, CA (US);

Inventors:

Cesar Ovalles, Walnut Creek, CA (US);

Estrella Rogel, Orinda, CA (US);

Ian Phillip Benson, The Woodlands, TX (US);

Ronald A. Behrens, Bakersfield, CA (US);

Assignee:

CHEVRON U.S.A. INC., San Ramon, CA (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C09K 8/594 (2006.01); E21B 43/26 (2006.01); E21B 43/24 (2006.01); E21B 43/38 (2006.01); C09K 8/62 (2006.01);
U.S. Cl.
CPC ...
C09K 8/594 (2013.01); C09K 8/62 (2013.01); E21B 43/24 (2013.01); E21B 43/26 (2013.01); E21B 43/38 (2013.01);
Abstract

In-situ upgrading of heavy hydrocarbons includes injecting into a reservoir solvent, an asphaltene precipitant additive and optionally steam, at a ratio of solvent to heavy hydrocarbon between 0.1:1 and 20:1 under reservoir conditions. The additive has C—H, C—C and/or C—O bonds that thermally crack to generate free radicals in the vapor phase after injection. Formed downhole are a blend containing an upgraded hydrocarbon, and precipitated asphaltenes. The upgraded hydrocarbon is produced such that the precipitated asphaltenes remain in the reservoir. The upgraded hydrocarbon has a greater API gravity, lower asphaltene content, and lower viscosity than the heavy hydrocarbon. The precipitated asphaltenes are present in a higher amount than a similar blend not containing the additive. A method for selecting the additive includes identifying candidate additives having bonds that crack to generate free radicals in the vapor phase at the operating temperature, and calculating percent increase of asphaltenes precipitated for each.


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