The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Apr. 13, 2021

Filed:

Dec. 06, 2016
Applicants:

LI Jia, Hudson, OH (US);

Xiaofei Jia, Akron, OH (US);

Inventors:

Li Jia, Hudson, OH (US);

Xiaofei Jia, Akron, OH (US);

Assignee:

The University of Akron, Akron, OH (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C08G 67/02 (2006.01); C08G 65/26 (2006.01); B01J 31/24 (2006.01); B01J 31/28 (2006.01); C08L 23/08 (2006.01);
U.S. Cl.
CPC ...
C08G 67/02 (2013.01); B01J 31/2404 (2013.01); B01J 31/28 (2013.01); C08G 65/26 (2013.01); C08G 65/2603 (2013.01); C08L 23/0884 (2013.01); B01J 2531/847 (2013.01); C08G 2650/40 (2013.01); C08L 2205/03 (2013.01);
Abstract

In various embodiments, the present invention is directed to terpolymers of carbon monoxide (CO), olefins (alkenes), and epoxides, as well as related methods and catalysts for their making and use. These terpolymer chains are comprised of ketone repeat units, ester repeat units, and ether repeat units. The additional presence of the ester repeat units and ether repeat units have the effect of lowering terpolymer melt temperature relative to that of similar polyketone, thus separating melt temperature from decomposition temperature, making it suitable for melt processing. In a single reaction mixture, the same metal catalyst that polymerizes CO with olefins also incorporates epoxide monomers into the terpolymer in the form of ester or ester and ether linkages. As a part of the terpolymer chain, the ester groups can undergo hydrolysis, rendering these terpolymer compositions hydrolytically degradable.


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