The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Mar. 09, 2021

Filed:

Jul. 23, 2019
Applicant:

Chevron Phillips Chemical Company Lp, The Woodlands, TX (US);

Inventors:

Pasquale Iacono, Bartlesville, OK (US);

Mark L. Hlavinka, Tulsa, OK (US);

Assignee:

Chevron Phillips Chemical Company, LP, The Woodlands, TX (US);

Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 51/15 (2006.01);
U.S. Cl.
CPC ...
C07C 51/15 (2013.01); C07C 51/15 (2013.01); C07C 57/04 (2013.01);
Abstract

This disclosure provides routes of synthesis of acrylic acid and other α,β-unsaturated carboxylic acids and their salts, including catalytic methods. In an aspect, there is provided a process for producing an α,β-unsaturated carboxylic acid or a salt thereof, the process comprising: (1) contacting in any order a group 8-11 transition metal precursor compound comprising at least one first ligand, at least one second ligand, an olefin, carbon dioxide, a diluent, and an anionic polyaromatic resin with associated metal cations to provide a reaction mixture; and (2) applying conditions to the reaction mixture suitable to produce the α,β-unsaturated carboxylic acid or a salt thereof. Methods of regenerating the polyaromatic resin with associated metal cations are described.


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