The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 23, 2021

Filed:

Mar. 22, 2018
Applicant:

Qatar Foundation for Education, Science and Community Development, Doha, QA;

Inventors:

Mohammed Al-Hashimi, Doha, QA;

Hugo Bronstein, London, GB;

Attorneys:
Primary Examiner:
Int. Cl.
CPC ...
C08G 61/12 (2006.01); H01L 51/00 (2006.01); H01L 51/05 (2006.01); H01L 51/42 (2006.01);
U.S. Cl.
CPC ...
C08G 61/126 (2013.01); C08G 61/123 (2013.01); C08G 61/124 (2013.01); H01L 51/0035 (2013.01); H01L 51/0036 (2013.01); C08G 2261/11 (2013.01); C08G 2261/1412 (2013.01); C08G 2261/18 (2013.01); C08G 2261/417 (2013.01); C08G 2261/91 (2013.01); C08G 2261/92 (2013.01); H01L 51/0558 (2013.01); H01L 51/4253 (2013.01);
Abstract

The method of making a pyrrolo bisthiazole homopolymer starts with dissolving a dibrominated pyrrolo[3,2-d:4,5-d']bisthiazole monomer having the formula: where R is an alkyl group, in anhydrous tetrahydrofuran (THF). Then, the solvated monomer is treated with 1 equivalent of a Turbo-Grignard reagent complex having the formulaPrMgCl.LiCl at 0° C. to form a reaction mixture. The reaction mixture is stirred for 1 hour at room temperature, and after stirring, the reaction mixture is refluxed for 24 hours. A conjugated homopolymer product having the formula: where n is the number of repeating units of pyrrolo[3,2-:4,5-′]bisthiazole, is recovered from the reaction mixture. The PBTz-based homopolymers showed broad absorption from 450 to 850 nm in thin film and excellent photochemical and thermal stability, making the polymers suitable for lightweight, low cost plastic electronic devices.


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