The patent badge is an abbreviated version of the USPTO patent document. The patent badge does contain a link to the full patent document.

The patent badge is an abbreviated version of the USPTO patent document. The patent badge covers the following: Patent number, Date patent was issued, Date patent was filed, Title of the patent, Applicant, Inventor, Assignee, Attorney firm, Primary examiner, Assistant examiner, CPCs, and Abstract. The patent badge does contain a link to the full patent document (in Adobe Acrobat format, aka pdf). To download or print any patent click here.

Date of Patent:
Feb. 16, 2021

Filed:

Sep. 29, 2017
Applicant:

Regents of the University of Minnesota, Minneapolis, MN (US);

Inventors:

Omar A. Abdelrahman, Minneapolis, MN (US);

Charles S. Spanjers, Minneapolis, MN (US);

Dae Sung Park, Minneapolis, MN (US);

Michael Tsapatsis, Edina, MN (US);

Limin Ren, Minneapolis, MN (US);

Paul J. Dauenhauer, Shoreview, MN (US);

Assignee:
Attorney:
Primary Examiner:
Int. Cl.
CPC ...
C07C 1/24 (2006.01); B01J 29/85 (2006.01); B01J 29/40 (2006.01); B01J 29/70 (2006.01); B01J 37/28 (2006.01); C07C 2/86 (2006.01); C07C 6/06 (2006.01); C07C 51/42 (2006.01);
U.S. Cl.
CPC ...
B01J 29/85 (2013.01); B01J 29/40 (2013.01); B01J 29/7007 (2013.01); B01J 37/28 (2013.01); C07C 1/24 (2013.01); C07C 2/865 (2013.01); C07C 6/06 (2013.01); C07C 51/42 (2013.01); B01J 2229/37 (2013.01); C07C 2521/04 (2013.01); C07C 2521/06 (2013.01); C07C 2521/08 (2013.01); C07C 2521/10 (2013.01); C07C 2521/12 (2013.01); C07C 2521/18 (2013.01); C07C 2523/10 (2013.01); C07C 2523/20 (2013.01); C07C 2527/167 (2013.01); C07C 2527/18 (2013.01); C07C 2527/188 (2013.01); C07C 2529/08 (2013.01); C07C 2529/40 (2013.01); C07C 2529/70 (2013.01);
Abstract

Forming a diene includes contacting a reactant including at least one of a cyclic ether and a diol with a heterogeneous acid catalyst to yield a reaction mixture including a diene. The heterogeneous acid catalyst includes at least one of a Lewis acid catalyst, a supported Lewis-acid catalyst, a Brnsted acid catalyst, a solid acid catalyst, a supported phosphoric acid catalyst, and a sulfonated catalyst. The dehydration of cyclic ethers and diols with high selectivity to yield dienes completes pathways for the production of dienes, such as isoprene and butadiene, from biomass in high yields, thereby promoting economical production of dienes from renewable resources.


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